Social Media Means
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Who got 400 million followers on Instagram?

UNBELIEVABLE! Lionel Messi becomes second person to reach 400 million followers on Instagram - Sports News.

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Argentine superstar Lionel Messi cemented his legacy as one of the greatest of all time on Sunday after his side beat France to win the FIFA World Cup. While Messi achieved the biggest milestone he aspired to achieve, he hit another one albeit in the digital space. Messi became the second person in internet history to reach the 400 million followers mark on Instagram behind his rival Cristiano Ronaldo. The Argentine magician managed to gain more than 24 million followers since the World Cup began after his pre-tournament tally stood at 376 million. Messi reached another landmark when his first celebratory post after the World Cup win became the most-liked Instagram post by a sportsperson. The post, so far, has amassed more than 57 million likes and has overtaken Ronaldo's post of him and Messi playing chess for an advertisement campaign. "WORLD CHAMPIONS!!!!!!! I dreamed it so many times, I wanted it so much that I still haven't fallen, I can't believe it," read the post. "Thank you very much to my family, to all who support me and also to all who believed in us. We demonstrate once again that Argentines when we fight together and united we are capable of achieving what we set out to do. The merit belongs to this group, which is above individualities, it is the strength of all fighting for the same dream that was also the dream of all Argentines... We did it!!! GO ARGENTINA!!!!! we are seeing each other very soon," it added. Messi was instrumental in Argentina reaching the final of the quadrennial event and played an even more significant part in the summit clash by dispatching two goals. After Argentina lost the first match against Saudi Arabia, rather shockingly, it was Messi that promised his fans that he will not let them down. True to his words, Messi managed to inspire his team to go on a winning streak thereon and demolish opponents along the way. Messi ended the tournament with 7 goals and 3 assists, becoming the proud owner of the Golden Ball award, his second at the World Cup finals.

(With inputs from agencies)

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What happens if KC is greater than Q?

If K > Q, a reaction will proceed forward, converting reactants into products. If K < Q, the reaction will proceed in the reverse direction, converting products into reactants.

Calculating the Reaction Quotient, Q

The expression for the reaction quotient, Q, looks like that used to calculate an equilibrium constant but Q can be calculated for any set of conditions, not just for equilibrium. Q can be used to determine which direction a reaction will shift to reach equilibrium. If K > Q, a reaction will proceed forward, converting reactants into products. If K < Q, the reaction will proceed in the reverse direction, converting products into reactants. If Q = K then the system is already at equilibrium.

In order to determine Q we need to know:

the equation for the reaction, including the physical states,

the quantities of each species (molarities and/or pressures), all measured at the same moment in time.

Write the expression for the reaction quotient.

Find the molar concentrations or partial pressures of each species involved.

Subsitute values into the expression and solve.

2

2

2

2

SO 2 Cl 2 (g) SO 2 (g) + Cl 2 (g) K c = 0.078 at 100oC

Write the expression to find the reaction quotient, Q.

Since K c is given, the amounts must be expressed as moles per liter (molarity). The amounts are in moles so a conversion is required. 0.500 mole SO 2 Cl 2 /5.00 L = 0.100 M SO 2 Cl 2 0.035 mole SO 2 /5.00 L = 0.070 M SO 2 0.080 mole Cl 2 /5.00 L = 0.016 M Cl 2 is given, the amounts must be expressed as moles per liter (molarity). The amounts are in moles so a conversion is required. Substitute the values in to the expression and solve for Q. Compare the answer to the value for the equilibrium constant and predict the shift.

0.078 (K) > 0.011 (Q)

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